ISC, CAS, Google Scholar     h-index: 20

Document Type : Original Research Article

Authors

1 Chemistry Department, Faculty of Science, Misurata University, Misurata, Libya

2 General Electricity Company of Libya, Misurata, Libya

3 Chemistry Department, Faculty of Science, University of Benghazi, Benghazi, Libya

10.33945/SAMI/PCBR.2019.2.3

Abstract

The purpose of the present study was to evaluate the concentrations of Mn, Cr, Fe, Cu, Zn, Pb, and Cd in 18 types of commercially available coffee, tea, and cocoa on Misurata city markets. The samples were dry digested and then measured by Microwave Plasma-Atomic Emission Spectrometry (MP-AES). The heavy elements levels were differed among the various types of analyzed samples. The concentrations of Mn were relatively higher than the other analyzed elements and varied between 1.0 – 673.3 mg/kg. The observed concentration ranges of the other elements, were as follows: Cr (0.1- 131.0 mg/kg), Fe (0.3 – 40.6 mg/kg), Cu (0.3 – 13.6 mg/kg), Zn (1.0 -20.9 mg/kg), Pb (1.8 – 4.4 mg/kg) and most Cd samples were below the instrument detection limits. The values determined for Mn, Cr, Fe, Cu, and Zn were lower than the maximum permissible limits. However, the concentrations of Pb were high according to the Brazilian law and Mercosul regulations, and the regulations of the European Union. Monitoring of heavy metal in food, like coffee, teas, and cocoa, provides useful information on safety features of food in regulatory procedures in terms of suitability of food for consumption, as well as its nutritional value.

Graphical Abstract

Heavy Metals Contents in Some Commercially available Coffee, Tea, and Cocoa Samples in Misurata City – Libya

Keywords

 References
[1] M.T. Pigozzi, F.R. Passos and F.Q. Mendes, Quality of Commercial Coffees: Heavy Metal and Ash Contents. Journal of food quality,  2018 (2018)  7.
[2] Z.N. Garba, S. Ubam, A.A. Babando and A. Galadima, Quantitative assessment of heavy metals from selected tea brands marketed in Zaria, Nigeria. Journal of Physical Science,  26 (2015)  43.
[3] I. Narin, H. Colak, O. Turkoglu, M. Soylak and M. Dogan, Heavy metals in black tea samples produced in Turkey. Bulletin of Environmental Contamination and Toxicology,  72 (2004)  844-849.
[4] D. Amankwaah, W. Nnuro, J. Awudza and S. Afful, Determination of heavy metals in cocoa beans from some major cocoa growing regions in Ghana. Food Science and Technology,  16 (2015)  225.
[5] A. Kumar, A. Nair, A. Reddy and A. Garg, Availability of essential elements in Indian and US tea brands. Food Chemistry,  89 (2005)  441-448.
[6] K.M. Elsherif, R.A.A. Khater and F.A. Hegaig, Determination of major and minor elements in dairy products produced in Misurata city–Libya. Maghrebian Journal of Pure and Applied Science,  3 3-2 (2017) 09-17.
[7] M. Najah, K. Elsherif, E. Kawan and N. Fara, Phytochemical screening and Heavy metals contents of Nicotiana Gluca plant, ijppr. Human,  4 (2015)  82-91.
[8] C. Ibeto and C. Okoye, High levels of Heavy metals in Blood of Urban population in Nigeria. Research Journal of Environmental Sciences,  4 (2010)  371-382.
[9] K.M. Elsherif and H.-M. Kuss, Simultaneous Multi-Element Determination of Bismuth (Bi), Antimony (Sb), and Selenium (Se). Advances in Applied Science Research,  3 (2012)  2402-2412.
[10] K. Elsherif and H. Kuss, Direct and Simultaneous Determination of Bismuth, Antimony, and Lead in Biological samples by Multi Element Electrothermal Atomic Absorption Spectrometer. Der Chem Sin, 3 (3), (2012)  727-736.
[11] K.M. Elsherif, A.A. Benkhayal, N. Bader and H.-M. Kuss, Multi-Element Determination of Cu, Mn, and Se using Electrothermal Atomic Absorption Spectrometry. IOSR Journal of Applied Chemistry,  6 (2013)  53-57.
[12] M.H. Rashid, Z. Fardous, M.A.Z. Chowdhury, M.K. Alam, M.L. Bari, M. Moniruzzaman and S.H. Gan, Determination of heavy metals in the soils of tea plantations and in fresh and processed tea leaves: an evaluation of six digestion methods. Chemistry Central Journal,  10 (2016)  7.
[13] M.A. Morgano, L.F. Pauluci, D.M.B. Mantovani and E.E.M. Mory, Mineral determination in green coffe. Food Science and Technology,  22 (2002)  19-23.
[14] M. Xie, A. Von Bohlen, R. Klockenkämper, X. Jian and K. Günther, Multielement analysis of Chinese tea (Camellia sinensis) by total-reflection X-ray fluorescence. Zeitschrift für Lebensmitteluntersuchung und-Forschung A,  207 (1998)  31-38.
[15] A. Nędzarek, A. Tórz, B. Karakiewicz, J.S. Clark, M. Laszczyńska, A. Kaleta and G. Adler, Concentrations of heavy metals (Mn, Co, Ni, Cr, Ag, Pb) in coffee. Acta Biochimica Polonica,  60 (2013) 
[16] N. Alagić and J. Huremović, Determination of metal contents in various chocolate samples. Glas. Hem. Technol. Bosne Herceg,  45 (2015)  39-42.
[17] A.D. Mooradian, M. Failla, B. Hoogwerf, M. Maryniuk and J. Wylie-Rosett, Selected vitamins and minerals in diabetes. Diabetes care,  17 (1994)  464-479.
[18] R. Jalilian and A. Taheri, Synthesis and application of a novel core-shell-shell magnetic ion imprinted polymer as a selective adsorbent of trace amounts of silver ions. e-Polymers,  18 (2018)  123-134.
[19] G. Karimi, M. Hasanzadeh, A. Nili, Z. Khashayarmanesh, Z. Samiei, F. Nazari and M. Teimuri, Concentrations and health risk of heavy metals in tea samples marketed in Iran. Pharmacology,  3 (2008)  164-174.
[20] N. Soliman, Metals contents in black tea and evaluation of potential human health risks to consumers. Health Economics & Outcome Research: Open Access,  2 (2016)  1-4.
[21] J.S. dos Santos, M.L.P. dos Santos, M.M. Conti, S.N. dos Santos and E. de Oliveira, Evaluation of some metals in Brazilian coffees cultivated during the process of conversion from conventional to organic agriculture. Food chemistry,  115 (2009)  1405-1410.
[22] N. Yousefi, A. Jahangard and M.H. Mahmoudian, Heavy Metal Concentration in Black Tea in Iran. Archives of Hygiene Sciences,  6 (2017)  128-135.
[23] L. Ferrara, D. Montesano and A. Senatore, The distribution of minerals and flavonoids in the tea plant (Camellia sinensis). Il farmaco,  56 (2001)  397-401.
[24] M. Grembecka, E. Malinowska and P. Szefer, Differentiation of market coffee and its infusions in view of their mineral composition. Science of the Total Environment,  383 (2007)  59-69.
[25] M.A. Nkansah, F. Opoku and A.A. Ackumey, Risk assessment of mineral and heavy metal content of selected tea products from the Ghanaian market. Environmental monitoring and assessment,  188 (2016)  332.
[26] S.A. da Silva, F. Mendes, i. Queiroz, M.R. Reis, F.R. Passos, A.M.X. de Carvalho, K.R. de Oliveira Rocha and F.G. Pinto, Determination of heavy metals in the roasted and ground coffee beans and brew. African Journal of Agricultural Research,  12 (2017)  221-228.
[27] Q.A. Nogaim, S. Al-Dalali, A. Al-Badany and M. Farh, Scientia Research Library. Journal of Applied Chemistry,  2 (2014)  13-18.
[28] S. Seenivasan, N. Manikandan, N.N. Muraleedharan and R. Selvasundaram, Heavy metal content of black teas from south India. Food control,  19 (2008)  746-749.
[29] M. Elbagermi, A. Alajtal and H. Edwards, Quantitative determination of heavy metal concentrations in herbal teas marketed in various countries including Libya. Asian Journal of Research in Biochemistry, (2017)  1-10.
[30] W. Ashraf and A.A. Mian, Levels of selected heavy metals in black tea varieties consumed in Saudi Arabia. Bulletin of environmental contamination and toxicology,  81 (2008)  101-104.
[31] F.-M. Shen and H.-W. Chen, Element composition of tea leaves and tea infusions and its impact on health. Bulletin of Environmental Contamination and Toxicology,  80 (2008)  300-304.
[32] M. Eldefrawy, E.G.A. Gomaa, S. Salem and F. Abdel Razik, Cyclic Voltammetric studies of calcium acetate salt with Methylene blue (MB) Using Gold Electrode. Progress in Chemical and Biochemical Research,  01 (2018)  11-18.
[33] E.G.A. Gomaa, M.A. Berghout, M.R. Moustafa, F.M. El Taweel and H.M. Farid, Thermodynamic and Theoretical solvation parameters for 2-amino-4,5-dimethylthiophene-3-carboxamide(ADTC) in Ethanol and Mixed EtOH-H2O solvents. Progress in Chemical and Biochemical Research,  01 (2018)  19-28.
[34] O. Solomon, W. Rabiu Saidu Umar, H. Sanusi Wara, A. Sadiq Yakubu, M. Michael Azubuike, M. Asugu Mary and H. Louis, Antiulcerogenic Activity of methanol extract and solvent fractions of Stem Bark of Lannea acida (A. Rich) Against Ethanol-Induced Gastric Mucosal Injury in Albino Rats. Progress in Chemical and Biochemical Research,  01 (2018)  29-39.
[35] C.W. Rankin, J.O. Nriagu, J.K. Aggarwal, T.A. Arowolo, K. Adebayo and A.R. Flegal, Lead contamination in cocoa and cocoa products: isotopic evidence of global contamination. Environmental health perspectives,  113 (2005)  1344-1348.
[36] H.H. Sandstead, Understanding zinc: recent observations and interpretations. The Journal of laboratory and clinical medicine,  124 (1994)  322-327.
[37] M.K. Aadesariya, V.R. Ram and P.N. Dave, Investigation of phytochemicals in methanolic leaves extracts of Abutilon pannosum and Grewia tenax by Q-TOF LC/MS. Progress in Chemical and Biochemical Research,  02 (2019)  13-19.
[38] A. El-Khateeb, M.H. Mahmoud and M. Fakih, Comparative study on different horizontal subsurface substrates in flow wetlands. Progress in Chemical and Biochemical Research,  02 (2019)  20-23.
[39] A.S. Zaek, B.A. Benhamed, M.A. Al shahomy, R. kamour and A. Eshames, Comparative study of pharmaceutical content of three different cardio vascular system drugs marketed in Tripoli- Libya. Progress in Chemical and Biochemical Research,  02 (2019)  6-12.
[40] M.A.T.A. SALMON, CE Moody, PW Reno and AE Gagliardi Department of Microbiology. Immunochemical Approaches to Coastal, Estuarine and Oceanographic Questions,  25 (2013)  318.
[41] H. Matsuura, A. Hokura, F. Katsuki, A. Itoh and H. Haraguchi, Multielement determination and speciation of major-to-trace elements in black tea leaves by ICP-AES and ICP-MS with the aid of size exclusion chromatography. Analytical sciences,  17 (2001)  391-398.
[42] M.H. Fekri, Study of Electrochemical and Electronical Properties on the Some Schiff Base Ni Complexes in DMSO Solvent by Computational Methods. Advanced Journal of Chemistry-Section A,  2 (2019)  14-20.
[43] M.M. Heravi, H. Abdi Oskooie, Z. Latifi and H. Hamidi, One-Pot Synthesis of Tetracyanocyclopropane Derivatives Using Hexamethylenetetramine-Bromine (HMTAB). Advanced Journal of Chemistry-Section A,  1 (2018)  7-11.
[44] W.E. John, A.A. Ayi, C. Anyama, P.B. Ashishie and B.E. Inah, On the use of methylimidazolium acetate ionic liquids as solvent and stabilizer in the synthesis of cobalt nanoparticles by chemical reduction method. Advanced Journal of Chemistry-Section A,  2 (2019)  175-183.